Green ammonia synthesis using CeO2/RuO2 nanolayers on vertical graphene catalyst via electrochemical route in alkaline electrolyte

Author:

Ju HyungKuk12,Seo Dong Han34ORCID,Chung Sunki567ORCID,Mao Xin8,An Byeong-Seon9,Musameh Mustafa10,Gengenbach Thomas R.10,Shon Hokyong3,Du Aijun8ORCID,Bendavid Avi11,Ostrikov Kostya (Ken)8ORCID,Yoon Hyung Chul12ORCID,Lee Jaeyoung567ORCID,Giddey Sarbjit2

Affiliation:

1. Hydrogen Research Department, Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon 34129, Republic of Korea

2. CSIRO Energy, Private Bag 10, Clayton South, Victoria, 3169, Australia

3. School of Civil and Environmental Engineering, University of Technology Sydney, P.O. Box 123, 15 Broadway, NSW, 2007, Australia

4. Korea Institute of Energy Technology (KENTECH), Naju, Republic of Korea

5. School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 61005, Republic of Korea

6. International Future Research Center of Chemical Energy Storage and Conversion Processes, GIST, Gwangju 61005, Republic of Korea

7. Ertl Centre for Electrochemistry and Catalysis, GIST, Gwangju 61005, Republic of Korea

8. School of Chemistry and Physics and Centre for Materials Science, Queensland University of Technology (QUT), Brisbane, 4000, Australia

9. Platform Technology Laboratory, Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon 34129, Republic of Korea

10. CSIRO Manufacturing, Private Bag 10, Clayton South, VIC 3169, Australia

11. CSIRO Manufacturing, PO Box 218, Lindfield, NSW 2070, Australia

12. Climate Change Research Division, Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon 34129, Republic of Korea

Abstract

The electrochemical synthesis of ammonia using nanolayered catalyst of RuO2 and CeO2 on a 3D-Graphene support at an ambient condition, demonstrates excellent NRR activity with long-term stability.

Funder

Commonwealth Scientific and Industrial Research Organisation

Australian Research Council

University of Technology Sydney

Korea Institute of Energy Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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