A novel bifunctional thioarsenate based on unprecedented molecular [Cd4As8Se16(Se2)2]8− cluster anions-Reference-Cited by-同舟云学术

A novel bifunctional thioarsenate based on unprecedented molecular [Cd₄As₈Se₁₆(Se₂)₂]⁸⁻ cluster anions

Published:2023 Issue:81 Volume:59 Page:12124-12127
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Xin¹,Zhou Sheng-Hua²³⁴,Zhang Chao¹,Lin Hua²³^ORCID,Liu Yi¹^ORCID

Affiliation:

1. Institute for Composites Science Innovation (InCSI), School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

2. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, Fujian 350108, China

3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

4. University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A novel molecular quaternary thioarsenate, Cs2CdAsSe5, possesses an unprecedented windmill-like [Cd4As4Se16(Se2)2]8− cluster and exhibits remarkable photocurrent response and large birefringence.

Funder

National Natural Science Foundation of China

Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China

Natural Science Foundation of Fujian Province

Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC03538G

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