Trapped in the coordination sphere: nitrate ion transfer driven by the cerium(iii/iv) redox couple
Author:
Affiliation:
1. Chemical Sciences and Engineering Division
2. Argonne National Laboratory
3. Argonne
4. USA
5. APS X-ray Science Division
Abstract
The electrochemical transfer of nitrate anions between oil and water phases—driven by the reduction and oxidation of cerium coordination complexes in oil phases—provides a new entry into chemical separations where an electrode potential tunes solute transfer between phases by ‘trapping’ the migrating anion on the cerium cation.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP06528G
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