The degree of electron itinerancy and shell closing in the core-ionized state of transition metals probed by Auger-photoelectron coincidence spectroscopy

Author:

Born Artur123,Johansson Fredrik O. L.45ORCID,Leitner Torsten12,Bidermane Ieva12,Kühn Danilo12,Mårtensson Nils16,Föhlisch Alexander123ORCID

Affiliation:

1. Uppsala-Berlin Joint Laboratory on Next Generation Photoelectron Spectroscopy, Albert-Einstein-Str. 15, 12489, Berlin, Germany

2. Institute for Methods and Instrumentation in Synchrotron Radiation Research FG-ISRR, Helmholtz-Zentrum Berlin für Materialien und Energie Albert-Einstein-Strasse 15, 12489, Berlin, Germany

3. Institut für Physik und Astronomie, Universität Potsdam, Karl-Liebknecht-Strasse 24-25, 14476, Potsdam, Germany

4. Division of Applied Physical Chemistry, Department of Chemistry, KTH – Royal Institute of Technology, SE-100 44, Stockholm, Sweden

5. Sorbonne Université, CNRS, Institut des NanoSciences de Paris, INSP, F-75005, Paris, France

6. Department of Physics and Astronomy, Division of X-ray Photon Science, Uppsala University, P. O. Box 256, SE-751 05, Uppsala, Sweden

Abstract

Auger-photoelectron coincidence spectroscopy affirms and clarifies the LVV spectrum of Cu to be atomic-like, Co itinerant and Ni mixed as predicted in the Cini–Sawatzky model.

Funder

Deutsche Forschungsgemeinschaft

Vetenskapsrådet

Carl Tryggers Stiftelse för Vetenskaplig Forskning

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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