Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes-Reference-Cited by-同舟云学术

Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

Published:2015 Issue:100 Volume:51 Page:17684-17687
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

López Aurora¹²³⁴,Parra Alejandro¹²³⁴,Jarava-Barrera Carlos¹²³⁴,Tortosa Mariola¹²³⁴

Affiliation:

1. Departamento de Química Orgánica

2. Universidad Autónoma de Madrid Cantoblanco

3. 28049 Madrid

4. Spain

Abstract

An efficient and general copper(i)-catalyzed silylation of p-quinone-methides is described. Non-symmetric dibenzylic silanes are obtained in high yields under mild reaction conditions. These compounds can be used as bench-stable benzylic carbanion precursors.

Funder

European Research Council

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC06653K

Reference67 articles.

1. H.-U. Wagner and R.Gompper, in The Chemistry of the Quinonoid Compounds, ed. S. Patai, Wiley, New York, 1974, ch. 18, vol. 2, p. 1145

2. para-Quinone Methide: a New Player in Asymmetric Catalysis

3. The Emergence of Quinone Methides in Asymmetric Organocatalysis

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