Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols-Reference-Cited by-同舟云学术

Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols

Published:2019 Issue:6 Volume:55 Page:786-789
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

León Félix¹²³,Francos Javier⁴⁵³,López-Serrano Joaquín¹²³^ORCID,García-Garrido Sergio E.⁴⁵³^ORCID,Cadierno Victorio⁴⁵³^ORCID,Pizzano Antonio¹²³^ORCID

Affiliation:

1. Instituto de Investigaciones Químicas and Centro de Innovación en Química Avanzada (ORFEO-CINQA), CSIC and Universidad de Sevilla

2. 41092 Sevilla

3. Spain

4. Laboratorio de Compuestos Organometálicos y Catálisis (Unidad Asociada al CSIC), Centro de Innovación en Química Avanzada (ORFEO-CINQA), Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica “Enrique Moles”, Universidad de Oviedo

5. 33006 Oviedo

Abstract

Asymmetric hydrogenation of 1 is performed with good enantio- and diastereoselectivity with Rh-Duphos/BPE catalysts providing a self-breeding chirality process.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC09391A

Reference43 articles.

1. Stereoselective hydrogenations of aryl-substituted dienes

2. Asymmetric Hydrogenation of Unfunctionalized, Purely Alkyl-Substituted Olefins

3. Enantio- and Regioselective Ir-Catalyzed Hydrogenation of Di- and Trisubstituted Cycloalkenes

4. A direct preparation of acetyl-(S)-phenylalanyl-(S)-phenylalanine methyl ester by a double asymmetric hydrogenation

5. Enantioselective Synthesis of Diamino Dicarboxylic Acids

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