Nucleophile and base differentiation of pyridine with tetrahalocatechols and the formation of manganese(iii)-catecholate and pyridinium-catecholate complexes for the in situ generation of H2O2 from O2

Author:

Bakewell Nicholas1234,Thavarajah Rumintha1234,Motevalli Majid1234,Sheriff Tippu S.1234ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Queen Mary University of London

3. London

4. UK

Abstract

The structures of two novel pyridinium catecholates are reported by reaction of pyridine with tetrachloro-o-benzoquinone and tetrabromocatechol; with tetrachlorocatechol pyridine acts as a base with the structure of the pyridinium-catecholate salt reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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