Highly efficient metal(iii) porphyrin and salen complexes for the polymerization of rac-lactide under ambient conditions

Author:

Praban Siriwan12345ORCID,Piromjitpong Parichat12345ORCID,Balasanthiran Vagulejan678ORCID,Jayaraj Savithra910118ORCID,Chisholm Malcolm H.910118,Tantirungrotechai Jonggol12345ORCID,Phomphrai Khamphee1213141516ORCID

Affiliation:

1. Center for Catalysis

2. Department of Chemistry and Center of Excellence for Innovation in Chemistry

3. Faculty of Science

4. Mahidol University

5. Bangkok 10400

6. Monomer-Polymer and Dajac Labs

7. Ambler

8. USA

9. Department of Chemistry and Biochemistry

10. The Ohio State University

11. Columbus

12. Department of Materials Science and Engineering

13. School of Molecular Science and Engineering

14. Vidyasirimedhi Institute of Science and Technology

15. Wangchan

16. Thailand

Abstract

Metal(iii) complexes supported by porphyrin and salen ligands were highly efficient for rac-lactide polymerization at room temperature giving isotactic-enriched PLA.

Funder

Thailand Research Fund

Mahidol University

Vidyasirimedhi Institute of Science and Technology

National Nanotechnology Center

Ohio State University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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