1,2,4-Triazolyl-4-acetate: a ditopic ligand combining soft and hard donor sites in homometallic (AgI) and heterometallic (AgI/UVI) coordination polymers

Author:

Senchyk Ganna A.1ORCID,Lysenko Andrey B.1,Krautscheid Harald2ORCID,Rusanov Eduard B.3,Karbowiak Miroslaw4ORCID,Domasevitch Kostiantyn V.1ORCID

Affiliation:

1. Inorganic Chemistry Department, Taras Shevchenko National University of Kyiv, Volodymyrska Str. 64, Kyiv 01033, Ukraine

2. Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany

3. Institute of Organic Chemistry, Murmanska Str. 5, Kyiv, 02660, Ukraine

4. Faculty of Chemistry, University of Wroclaw, 14 Joliot-Curie Str, 50-383 Wroclaw, Poland

Abstract

A 1,2,4-triazol-4-yl-acetic acid (trGly-H) was used for the synthesis of AgI and AgI/UVI coordination polymers. The composition space diagram was built for the AgNO3/trGly-H/UO2(NO3)2·6H2O system shows the crystallization fields of two AgI/UVI-compounds were found.

Funder

National Research Foundation of Ukraine

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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