μ1,1-R-phenylcyanamido bridges as a new safe synthetic strategy for ferromagnetic molecular clusters-Reference-Cited by-同舟云学术

μ1,1-R-phenylcyanamido bridges as a new safe synthetic strategy for ferromagnetic molecular clusters

Published:2016 Issue:12 Volume:45 Page:5395-5403
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Speed Saskia¹²³⁴⁵,Casanovas Berta¹²³⁴,Vicente Ramon¹²³⁴

Affiliation:

1. Departament de Química Inorgànica

2. Universitat de Barcelona

3. 08028 Barcelona

4. Spain

5. Institut des Sciences Chimiques de Rennes

Abstract

Three new Ni(ii) defective double-cubane tetrameric entities in which the Ni(ii) atoms are linked by μ_1,1-R-phenylcyanamido bridges and two kinds of O-bridges have been reported. The magnetic data indicate ferromagnetic coupling through the R-phenylcyanamido ligands.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04306A

Reference32 articles.

1. Polynuclear NiII and MnII azido bridging complexes. Structural trends and magnetic behavior

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5. Azido-mediated systems showing different magnetic behaviors

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