Helical mesoporous silica as an inorganic heterogeneous chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess-Reference-Cited by-同舟云学术

Helical mesoporous silica as an inorganic heterogeneous chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess

Published:2015 Issue:42 Volume:51 Page:8742-8744
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kawasaki Tsuneomi¹²³⁴⁵,Araki Yuko¹²³⁴,Hatase Kunihiko¹²³⁴,Suzuki Kenta¹²³⁴,Matsumoto Arimasa¹²³⁴,Yokoi Toshiyuki⁶⁷⁸⁴,Kubota Yoshihiro⁹¹⁰¹¹⁴,Tatsumi Takashi⁶⁷⁸⁴,Soai Kenso¹²³⁴⁵

Affiliation:

1. Department of Applied Chemistry

2. Tokyo University of Science

3. Tokyo

4. Japan

5. Research Center for Chirality

6. Chemical Resources Laboratory

7. Tokyo Institute of Technology

8. Yokohama 226-8503

9. Division of Materials Science and Chemical Engineering

10. Yokohama National University

11. Yokohama

Abstract

P and M-Helical mesoporous silica was found to act as a chiral inorganic trigger for asymmetric autocatalysis to afford (S) and (R)-pyrimidyl alkanol with up to >99.5% ee, respectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC01750E

Reference58 articles.

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2. Comprehensive Asymmetric Catalysis I-III, ed. E. N. Jacobsen, A. Pfaltz and H. Yamamoto, Springer-Verlag, Berlin, 1999

3. Supported Chiral Catalysts on Inorganic Materials

4. Asymmetric Heterogeneous Catalysis

5. Heterogeneous enantioselective catalysts: strategies for the immobilisation of homogeneous catalysts

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