A self-assembled metal–organic framework for enhanced UO22+ fluorescence sensing: integration of an octa-nuclear zinc cluster with hexakis(4-carboxyphenoxy)cyclotriphosphazene

Author:

Chen Xi1ORCID,Chen Zi-tong2,Xu Shi-xian1,Chen Yuan2,Tong Jia-ping3ORCID,Li Bao2ORCID

Affiliation:

1. School of Chemistry and Environmental Science, Shangrao Normal University, Shangrao, Jiangxi, 334001, People's Republic of China

2. Key Laboratory of Material Chemistry for Energy Conversion and Storage, Semiconductor chemistry center, School of Chemistry and Chemical Engineering, Hubei Key Laboratory of Bioinorganic Chemistry & Materia Medica, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, People's Republic of China

3. Laboratory of Physicochemical Analysis, Training Base, Army Logistics Academy, Chongqing 400041, People's Republic of China

Abstract

A novel photoactive Zn-MOF was successfully synthesised by introducing a flexible cyclotriphosphonitrile hexacarboxylic acid, which achieves a sensitive fluorescence quenching response to radioactive UO22+ ions and the heavy metal Fe3+.

Funder

Education Department of Jiangxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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