The fluorite-like Ln5Mo3O16+δ family extension: LiLn4Mo3O15F (Ln = Eu, Gd, or Dy) ceramics-Reference-Cited by-同舟云学术

The fluorite-like Ln₅Mo₃O_16+δ family extension: LiLn₄Mo₃O₁₅F (Ln = Eu, Gd, or Dy) ceramics

Published:2023 Issue:40 Volume:47 Page:18729-18736
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Orlova Ekaterina¹²^ORCID,Sorokin Timofei²^ORCID,Pustovit Alexander³,Baldin Egor⁴^ORCID,Zakharova Elena³,Kharitonova Elena¹²,Lyskov Nikolay⁵⁶,Utochnikova Valentina³^ORCID,Alekseeva Olga²,Voronkova Valentina¹

Affiliation:

1. Lomonosov Moscow State University, Faculty of Physics, GSP-1, Leninskie Gory, Moscow, 119991, Russian Federation

2. Shubnikov Institute of Crystallography of Federal Scientific Research Centre ‘Crystallography and Photonics’ of Russian Academy of Sciences, Leninskii Prospekt 59, Moscow, 119333, Russian Federation

3. Lomonosov Moscow State University, Department of Chemistry, GSP-1, Leninskie Gory, Moscow, 119991, Russian Federation

4. N.N. Semenov Federal Research Center For Chemical Physics RAS, Kosygina 4, Moscow, 119991, Russian Federation

5. Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences, Acad. Semenov av. 1, Chernogolovka, 142432, Russian Federation

6. HSE University, ul. Myasnitskaya 20, 101000 Moscow, Russian Federation

Abstract

A detailed study of the physical properties of the new cubic LiEu4Mo3O15F phase has been conducted. This study reveals a reversible phase transition accompanied by a jump in anionic conductivity to a value of 10−2 S cm−1 at 700 °C in this material.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ03033D

Reference28 articles.

1. Oxide ion conductivity in Ln5Mo3O16+x) (Ln = La, Pr, Nd, Sm, Gd; x .apprx. 0.5) with a fluorite-related structure

2. Oxygen ion and electron conductivity in fluorite-like molybdates Nd 5 Mo 3 O 16 and Pr 5 Mo 3 O 16

3. The Fluorite-Like Phase Nd5Mo3O16±δ in the MoO3–Nd2O3 System: Synthesis, Crystal Structure, and Conducting Properties

4. Pr5Mo3O16 + δ: A New Anode Material for Solid Oxide Fuel Cells