Steric hindrance classified: treatment of isothiocyanatoallene with secondary amines bearing bulky substituents to generate 2-aminothiazoles-Reference-Cited by-同舟云学术

Steric hindrance classified: treatment of isothiocyanatoallene with secondary amines bearing bulky substituents to generate 2-aminothiazoles

Published:2019 Issue:20 Volume:6 Page:3517-3522
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Banert Klaus¹²³⁴^ORCID,Seifert Jennifer¹²³⁴

Affiliation:

1. Chemnitz University of Technology

2. Organic Chemistry

3. 09111 Chemnitz

4. Germany

Abstract

Based on the reaction of allenyl isothiocyanate with secondary amines, the influence of strong steric hindrance on the nucleophilicity of amines was measured.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00312F

Reference65 articles.

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3. Polar and Steric Substituent Constants for Aliphatic and o-Benzoate Groups from Rates of Esterification and Hydrolysis of Esters1

4. Steric effects—I

5. Steric effects. I. Esterification and acid-catalyzed hydrolysis of esters

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