A sterically congested 1,2-diphosphino-1′-boryl-ferrocene: synthesis, characterization and coordination to platinum

Author:

Lerayer Emmanuel1234,Renaut Patrice1234,Roger Julien1234ORCID,Pirio Nadine1234ORCID,Cattey Hélène1234ORCID,Fleurat-Lessard Paul1234ORCID,Boudjelel Maxime56784,Massou Stéphane9104,Bouhadir Ghenwa56784,Bourissou Didier56784ORCID,Hierso Jean-Cyrille123411ORCID

Affiliation:

1. Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB-UMR CNRS 6302)

2. Université de Bourgogne Franche-Comté

3. 21078 Dijon

4. France

5. Laboratoire Hétérochimie Fondamentale et Appliquée (UMR 5069)

6. Université de Toulouse

7. CNRS

8. 31062 Toulouse Cedex 9

9. Institut de Chimie de Toulouse (FR 2599)

10. 31062 Toulouse Cedex 09

11. Institut Universitaire de France (IUF)

Abstract

A unique tritopic (P, P, B)-ferrocene ambiphile with antagonist functions directly attached to a metallocene backbone is described.

Funder

Agence Nationale de la Recherche

Conseil régional de Bourgogne-Franche-Comté

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference52 articles.

1. Phosphine-Boranes and Related Ambiphilic Compounds

2. Frustrated Lewis Pairs I and II, Topics in Current Chemistry , ed. D. W. Stephan and G. Erker , Springer , Heidelberg, New York, Dordrecht, London , 2013 , vol. 332 and 334

3. Ambiphilic Molecules: From Organometallic Curiosity to Metal-Free Catalysts

4. Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

5. Frustrated Lewis Pair Chemistry: Development and Perspectives

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