Concomitant emergence of circularly polarized luminescence and single-molecule magnet behavior in chiral-at-metal Dy complex

Author:

El Rez Bahjat12345,Liu Jiawen63789,Béreau Virginie12345ORCID,Duhayon Carine12345,Horino Yuki10111213,Suzuki Takayoshi1011121314ORCID,Coolen Laurent63789,Sutter Jean-Pascal12345ORCID

Affiliation:

1. Laboratoire de Chimie de Coordination du CNRS (LCC-CNRS)

2. Université de Toulouse

3. CNRS

4. Toulouse

5. France

6. Sorbonne Université

7. Institut de NanoSciences de Paris

8. INSP

9. F-75005 Paris

10. Graduate School of Natural Science and Technology

11. Okayama University

12. Okayama 700-8530

13. Japan

14. Research Institute for Interdisciplinary Science (RIIS)

Abstract

Circularly polarized luminescence was evidence in solid state for a chiral-at-metal Dy(iii) single-molecule magnet. This CPL is opposite for the enantiomers and develops when the relaxation of the magnetization for the Dy becomes slower.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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