H/D solvent isotope effects on the photoracemization reaction of enantiomeric the tris(2,2′-bipyridine)ruthenium(ii) complex and its analogues
Author:
Affiliation:
1. Department of Materials Science
2. Graduate School of Nanobioscience
3. Yokohama City University
4. Kanazawa-ku
5. Japan
Abstract
This work assessed solvent isotope effects on the photoracemization rate and emission lifetime for [Ru(bpy)3]2+ (bpy = 2,2′-bipyridine) in water.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP06758B
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4. Expanded bite angles in tridentate ligands. Improving the photophysical properties in bistridentate RuII polypyridine complexes
5. Tuning the Electronics of Bis(tridentate)ruthenium(II) Complexes with Long-Lived Excited States: Modifications to the Ligand Skeleton beyond Classical Electron Donor or Electron Withdrawing Group Decorations
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