Enhancing SIM behaviour in a mononuclear tetrahedral [Co(N,N′-2-iminopyrrolyl)2] complex-Reference-Cited by-同舟云学术

Enhancing SIM behaviour in a mononuclear tetrahedral [Co(N,N′-2-iminopyrrolyl)₂] complex

Published:2022 Issue:69 Volume:58 Page:9682-9685
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ferreira Patrícia S.¹²^ORCID,Malta José F.²³^ORCID,Bandeira Nuno A. G.⁴^ORCID,Allgaier Alexander⁵,van Slageren Joris⁵^ORCID,Paixão José A.³,Almeida Manuel²^ORCID,Pereira Laura C. J.²^ORCID,Gomes Pedro T.¹^ORCID

Affiliation:

1. Centro de Química Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Química, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001, Lisboa, Portugal

2. Centro de Ciências e Tecnologias Nucleares, Departamento de Engenharia e Ciências Nucleares, Instituto Superior Técnico, Universidade de Lisboa, 2695-066, Bobadela LRS, Portugal

3. CFisUC – Centro de Física da Universidade de Coimbra, Departamento de Física, Universidade de Coimbra, 3004-516, Coimbra, Portugal

4. BioISI – Biosystems & Integrative Sciences Institute, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016, Lisboa, Portugal

5. Institut für Physikalische Chemie, Universität Stuttgart, Pfaffenwaldring 55, Stuttgart, D-70569, Germany

Abstract

Co(ii)–N4 complex displays slow magnetisation at zero static field, exhibiting a high spin-reversal energy barrier Ueff = 85 cm−1.

Funder

European Regional Development Fund

Deutsche Forschungsgemeinschaft

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03511A

Reference21 articles.

1. The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

2. Slow Magnetic Relaxation in a High-Spin Iron(II) Complex

3. Slow Magnetic Relaxation at Zero Field in the Tetrahedral Complex [Co(SPh)4]2–

4. Slow magnetic relaxation in the tetrahedral cobalt(II) complexes [Co(EPh)4]2− (EO, S, Se)

5. A Mononuclear Transition Metal Single-Molecule Magnet in a Nuclear Spin-Free Ligand Environment

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