A sustainable strategic approach for N-alkylation of amines with activation of alcohols triggered via a hydrogen auto-transfer reaction using a Pd(ii) complex: evidence for metal–ligand cooperativity

Author:

Kumar Chaudhary Virendra1,Kukreti Prashant1,Sharma Keshav1ORCID,Kumar Kapil1,Singh Sain1ORCID,Kumari Sheela1,Ghosh Kaushik12ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, Uttarakhand, India

2. Department of Biosciences and Bioengineering, Indian Institute of Technology Roorkee, Roorkee 247667, Uttarakhand, India

Abstract

Palladium complex containing pincer bisazo-amine ligand was synthesized and characterized with various techniques. Complex was utilized to study the catalytic activity for the synthesis of amine derivatives via a hydrogen borrowing strategy.

Funder

Council of Scientific and Industrial Research, India

Ministry of Human Resource Development

University Grants Commission

Department of Science and Technology, Government of Kerala

Publisher

Royal Society of Chemistry (RSC)

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