The crucial role of silver(i)-salts as additives in C–H activation reactions: overall analysis of their versatility and applicability

Author:

de Carvalho Renato L.1ORCID,Diogo Emilay B. T.1ORCID,Homölle Simon L.2ORCID,Dana Suman2ORCID,da Silva Júnior Eufrânio N.1ORCID,Ackermann Lutz2ORCID

Affiliation:

1. Institute of Exact Sciences, Department of Chemistry, Federal University of Minas Gerais-UFMG, 31270-901, Belo Horizonte, MG, Brazil

2. Institut für Organische und Biomolekulare Chemie and Wöhler Research Institute for Sustainable Chemistry, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077 Göttingen, Germany

Abstract

This review discusses the important role of silver(i) salts as additives in transition-metal catalyzed C–H activation, and depicts the discussion about the current shift towards Ag-free procedures, as plausible and sustainable alternatives.

Funder

Alexander von Humboldt-Stiftung

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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