Triiron clusters derived from dinuclear complexes related to the active site of [Fe–Fe] hydrogenases: steric effect of the dithiolate bridge on redox properties, a DFT analysis-Reference-Cited by-同舟云学术

Triiron clusters derived from dinuclear complexes related to the active site of [Fe–Fe] hydrogenases: steric effect of the dithiolate bridge on redox properties, a DFT analysis

Published:2021 Issue:15 Volume:8 Page:3659-3674
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Hobballah Ahmad¹²³⁴,Arrigoni Federica⁵⁶⁷⁸^ORCID,Elleouet Catherine¹²³⁴,Greco Claudio⁹⁸^ORCID,Laurans Maxime¹²³⁴,Pétillon François Y.¹²³⁴,Schollhammer Philippe¹²³⁴^ORCID

Affiliation:

1. UMR CNRS 6521

2. Université de Bretagne Occidentale

3. Brest

4. France

5. Department of Biotechnology and Biosciences

6. University of Milan-Bicocca

7. 20126 Milan

8. Italy

9. Department of Earth and Environmental Sciences University of Milan-Bicocca

Abstract

CV and DFT calculations reveal that electrochemical behaviours of triiron clusters [Fe₃(CO)₅(κ₂-dppe)(μ-pdt^R2)(μ-pdt)] depend on the nature of the dithiolate bridge.

Funder

Centre National de la Recherche Scientifique

Université de Bretagne Occidentale

Università degli Studi di Milano-Bicocca

Région Bretagne

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QI/D1QI00006C

Reference79 articles.

1. X-ray Crystal Structure of the Fe-Only Hydrogenase (CpI) from Clostridium pasteurianum to 1.8 Angstrom Resolution

2. Desulfovibrio desulfuricans iron hydrogenase: the structure shows unusual coordination to an active site Fe binuclear center

3. Biomimetic assembly and activation of [FeFe]-hydrogenases

4. Bioinspired Catalysis: Metal-Sulfur Complexes , ed. W. Weigand , P. Schollhammer , Wiley-VCH-Verl , Weinheim , 2015 , pp. 417

5. C. Elleouet , F. Y.Pétillon and P.Schollhammer , in Advances in bioorganometallic chemistry : [FeFe]-hydrogenases Models , ed. T. Hirao and T. Moriuchi , Elsevier , 2019 , ch. 17, pp. 347–359

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Triiron Complexes Featuring Azadiphosphine Related to the Active Site of [FeFe]-Hydrogenases: Their Redox Behavior and Protonation;Molecules;2024-07-10

2. An unexpected leading role for [Fe2(CO)6(μ-pdt)] in our understanding of [FeFe]-H2ases and the search for clean hydrogen production;Coordination Chemistry Reviews;2023-09

3. Formation of polynuclear iron(III) complexes of N-(2-pyridylmethyl)iminodipropanol depending on pseudohalide ions: synthesis, crystal structure, and magnetic properties;Journal of Industrial and Engineering Chemistry;2022-06

4. Tri‐ and Tetra‐Substituted Derivatives of [Fe ₂ (CO) ₆ (μ‐dithiolate)] as Novel Dinuclear Platforms Related to the H‐Cluster of [FeFe]H ₂ ases;European Journal of Inorganic Chemistry;2022-04-14