Studies of structural diversity due to inter-/intra-molecular hydrogen bonding and photoluminescent properties in thiocarboxylate Cu(i) and Ag(i) complexes

Author:

Singh Suryabhan1234,Bhattacharya Subrato1234

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. Banaras Hindu University

4. Varanasi-221005, India

Abstract

Cu(I) and Ag(I) thiocarboxylate complexes containing 2-mercaptobenzimidazole and 2-mercapto-2-thiazoline were synthesized. Direction of H-bonding depends on the R-group of thiocarboxylate ligands. AIM and NBO (DFT) calculations revealed the nature of M-M interactions in complex 7.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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