Studies of structural diversity due to inter-/intra-molecular hydrogen bonding and photoluminescent properties in thiocarboxylate Cu(i) and Ag(i) complexes
Author:
Affiliation:
1. Department of Chemistry
2. Faculty of Science
3. Banaras Hindu University
4. Varanasi-221005, India
Abstract
Cu(I) and Ag(I) thiocarboxylate complexes containing 2-mercaptobenzimidazole and 2-mercapto-2-thiazoline were synthesized. Direction of H-bonding depends on the R-group of thiocarboxylate ligands. AIM and NBO (DFT) calculations revealed the nature of M-M interactions in complex 7.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA07883G
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