Modular O- vs. N-coordination of pyridylidene amide ligands to iron determines activity in alcohol oxidation catalysis-Reference-Cited by-同舟云学术

Modular O- vs. N-coordination of pyridylidene amide ligands to iron determines activity in alcohol oxidation catalysis

Published:2020 Issue:48 Volume:49 Page:17674-17682
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Verhoeven Dide G. A.¹²³⁴,Albrecht Martin¹²³⁴^ORCID

Affiliation:

1. Departement für Chemie und Biochemie

2. Universität Bern

3. CH-3012 Bern

4. Switzerland

Abstract

Pyridylidene amide (PYA) iron(ii) complexes were synthesized with different donor sets: the NN-bidentate PYA is unstable; the NNN set inhibits catalytic oxidation; while the ONO-tridentate pincer-type PYA promotes oxidation of alcohols and thiols.

Funder

FP7 Ideas: European Research Council

Universität Bern

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02818E

Reference40 articles.

1. Nitrogen Donors in Organometallic Chemistry and Homogeneous Catalysis

2. Extending the Range of Neutral N-Donor Ligands Available for Metal Catalysts: N-[1-Alkylpyridin-4(1H)-ylidene]amides in Palladium-Catalyzed Cross-Coupling Reactions

3. Selective CF Bond Activation of Tetrafluorobenzenes by Nickel(0) with a Nitrogen Donor Analogous to N-Heterocyclic Carbenes

4. Synthesis, Coordination Chemistry and Bonding of Strong N-Donor Ligands Incorporating the 1H-Pyridin-(2E)-Ylidene (PYE) Motif

5. Charged Behaviour from Neutral Ligands: Synthesis and Properties of N-Heterocyclic Pseudo-amides

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