Entropic stabilization plays a key role in the non-uniform distribution of oxygen ions and vacancy defects in gadolinium-doped ceria
Author:
Affiliation:
1. Department of Chemical Engineering
2. Indian Institute of Technology Bombay
3. Mumbai 400076
4. India
Abstract
A new theory describing oxygen ion movement and distribution in YSZ and GDC shows that entropic effects are significant.
Funder
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP03743E
Reference45 articles.
1. Appraisal of Ce1−yGdyO2−y/2 electrolytes for IT-SOFC operation at 500°C
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4. Defect cluster formation in M2O3-doped CeO2
5. Oxygen ion conductivity of the ceria-samarium oxide system with fluorite structure
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