Entangled core/shell magnetic structure driven by surface magnetic symmetry-breaking in Cr2O3 nanoparticles

Author:

Rinaldi-Montes Natalia1,Gorria Pedro2ORCID,Fuertes Antonio B.3ORCID,Martínez-Blanco David4,Amghouz Zakariae5ORCID,Puente-Orench Inés6,Olivi Luca7ORCID,Herrero-Martín Javier8,Fernandez-Garcia Maria Paz1,Alonso Javier9ORCID,Phan Manh-Huong10ORCID,Srikanth Hariharan10ORCID,Marti Xavi11,Blanco Jesús A.1ORCID

Affiliation:

1. Departamento de Física, Universidad de Oviedo, E-33007 Oviedo, Spain

2. Departamento de Física & IUTA, EPI, Universidad de Oviedo, E-33203 Gijón, Spain

3. Instituto Nacional del Carbón (CSIC), E-33080 Oviedo, Spain

4. Servicios Científico-Técnicos, Universidad de Oviedo, E-33006 Oviedo, Spain

5. Departamento de Ciencia de Materiales e Ingeniería Metalúrgica, Universidad de Oviedo, E-33004 Oviedo, Spain

6. Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza and Institut Laue-Langevin, BP 156, F-38042 Grenoble Cedex 9, France

7. Elettra-Sincrotrone Trieste S.C.p.A, 34149 Basovizza, Trieste, Italy

8. ALBA Synchrotron, 08290 Cerdanyola del Vallès, Barcelona, Spain

9. CITIMAC, Facultad de Ciencias, Universidad de Cantabria, E-39005, Santander, Spain

10. Department of Physics, University of South Florida, FL 33620, Tampa, USA

11. Institute of Physics, Czech Academy of Sciences, Cukrovarnická 10, 162 53, Prague 6, Czech Republic

Abstract

The entangled core/shell magnetic structure of Cr2O3 nanoparticles, where pinned uncompensated spins at the shell are randomly distributed in a low-temperature spin-glass ordering, gives rise to a Double Exchange-bias mechanism.

Funder

Fundación para el Fomento en Asturias de la Investigación Científica Aplicada y la Tecnología

Ministerio de Ciencia y Tecnología

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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