Diastereoselection during 1,2-addition of 3-bromomethyl-5H-furan-2-one to α-chiral aldehydes mediated by indium in aqueous and organic solvent systems: direct route to obtain optically active α-methylene-γ-butyrolactones-Reference-Cited by-同舟云学术

Diastereoselection during 1,2-addition of 3-bromomethyl-5H-furan-2-one to α-chiral aldehydes mediated by indium in aqueous and organic solvent systems: direct route to obtain optically active α-methylene-γ-butyrolactones

Published:2014 Issue:33 Volume:4 Page:17218-17221
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Zhang Fuhai¹²³⁴,Liu Yang¹²³⁴,Xie Longguan¹²³⁴,Xu Xiaohua¹²³⁴

Affiliation:

1. State Key Laboratory of Elemento-Organic Chemistry

2. Collaborative innovation center of chemical science and engineering

3. Nankai University

4. Tianjin 300071, China

Abstract

High chelation control or Felkin–Ahn selective allylic addition of2to α-hydroxyaldehydes or α-rigid aldehydes mediated by indium.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C3RA47773H

Reference19 articles.

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2. Asymmetric Induction. A Model for Additions to Carbonyls Directly Bonded to Asymmetric Carbons

3. Torsional strain involving partial bonds. The stereochemistry of the lithium aluminium hydride reduction of some simple open-chain ketones

4. Fundamental Mechanistic Characteristics and Synthetic Applications of Allylations Promoted by Indium Metal in Aqueous Media

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