Alteration of intramolecular electronic transition via deboronation of carbazole-based o-carboranyl compound and intriguing ‘turn-on’ emissive variation-Reference-Cited by-同舟云学术

Alteration of intramolecular electronic transition via deboronation of carbazole-based o-carboranyl compound and intriguing ‘turn-on’ emissive variation

Published:2021 Issue:39 Volume:11 Page:24057-24064
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Lee Seok Ho¹²³⁴⁵,Mun Min Sik¹²³⁴⁵,Kim Mingi¹²³⁴⁵,Lee Ji Hye¹²³⁴⁵^ORCID,Hwang Hyonseok¹²³⁴⁵^ORCID,Lee Wonchul¹²³⁴⁵^ORCID,Lee Kang Mun¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Institute for Molecular Science and Fusion Technology

3. Kangwon National University

4. Chuncheon

5. Republic of Korea

Abstract

Deboronation of a 9-methyl-9H-carbazole–based closo-o-carboranyl compound to the nido-o-carborane in an aqueous solution results in a ratiometric turn-on response in the deep-blue emission region with moderate reactivity.

Funder

National Research Foundation of Korea

Ministry of Science and ICT, South Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA03716A

Reference87 articles.

1. Dicarba-closo-dodecaboranes C2B10H12 and their derivatives

2. Carborane-Based Optoelectronically Active Organic Molecules: Wide Band Gap Host Materials for Blue Phosphorescence