The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe2-Reference-Cited by-同舟云学术

The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe2

Published:2014 Issue:47 Volume:50 Page:6214-6216
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Ascherl Laura¹²³⁴⁵,Nordheider Andreas¹²³,Arachchige Kasun S. Athukorala¹²³,Cordes David B.¹²³,Karaghiosoff Konstantin⁴⁵,Bühl Michael¹²³,Slawin Alexandra M. Z.¹²³,Woollins J. Derek¹²³

Affiliation:

1. School of Chemistry

2. University of St Andrews

3. , Scotland

4. Ludwig-Maximilians-Universität München

5. 81377 München, Germany

Abstract

Reaction of Woollins' reagent (WR) with pyridine yields the P(V) species PhPSe₂ stabilised by pyridine coordination. Its potential as a selenation reagent under mild conditions was shown by calculations and an experimental comparison to WR.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC01073F

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