Platinum on carbon-catalysed site-selective H–D exchange reaction of allylic alcohols using alkyl amines as a hydrogen source-Reference-Cited by-同舟云学术

Platinum on carbon-catalysed site-selective H–D exchange reaction of allylic alcohols using alkyl amines as a hydrogen source

Published:2022 Issue:7 Volume:9 Page:1986-1991
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Park Kwihwan¹,Oka Naoki²,Sawama Yoshinari²^ORCID,Ikawa Takashi¹,Yamada Tsuyoshi¹^ORCID,Sajiki Hironao¹^ORCID

Affiliation:

1. Laboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan

2. Graduate School of Pharmaceutical Sciences, Osaka University, Suita, Osaka 565-0871, Japan

Abstract

The platinum on carbon catalysed site-selective H–D exchange reaction of allylic alcohols in the presence of amylamine as a hydrogen source and deuterium oxide as a deuterium source was developed.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00177B

Reference56 articles.

1. Deuterium- and Tritium-Labelled Compounds: Applications in the Life Sciences

2. Pd- and Pt-catalyzed H/D exchange methods and their application for internal MS standard preparation from a Sanofi-Aventis perspective

3. The Renaissance of H/D Exchange

4. New Gateways to the Platinum Group Metal-Catalyzed Direct Deuterium-Labeling Method Utilizing Hydrogen as a Catalyst Activator

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