Late-stage modification of π-electron systems based on asymmetric oxidation of a medium-sized sulfur-containing ring

Author:

Hayakawa Masahiro12ORCID,Horike Satoshi1ORCID,Hijikata Yuh34ORCID,Yasui Kosuke1ORCID,Yamaguchi Shigehiro24ORCID,Fukazawa Aiko14ORCID

Affiliation:

1. Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Institute for Advanced Study, Kyoto University, Yoshida, Sakyo, Kyoto 606-8501, Japan

2. Department of Chemistry, Graduate School of Science and Integrated Research Consortium on Chemical Sciences (IRCCS), Nagoya University, Furo, Chikusa, Nagoya 464-8602, Japan

3. Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Kita 21, Nishi 10, Kita-ku, Sapporo 001-0021, Japan

4. Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Furo, Chikusa, Nagoya 464-8602, Japan

Abstract

The asymmetric oxidation of a sulfur-containing nine-membered heterocycle was achieved for the late-stage introduction of chirality to the substituents of π-electron systems.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Nickel‐Catalyzed Enantioselective Synthesis of Dienyl Sulfoxide;Angewandte Chemie International Edition;2023-12-27

2. Nickel‐Catalyzed Enantioselective Synthesis of Dienyl Sulfoxide;Angewandte Chemie;2023-12-27

3. Eight-membered and larger rings;Progress in Heterocyclic Chemistry;2023

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