Iodine passivation facilitates on-surface synthesis of robust regular conjugated two-dimensional organogold networks on Au(111)

Author:

Badami-Behjat Arash12,Galeotti Gianluca12,Gutzler Rico12,Pastoetter Dominik L.3ORCID,Heckl Wolfgang M.12,Feng Xinliang34ORCID,Lackinger Markus12ORCID

Affiliation:

1. Deutsches Museum, Museumsinsel 1, 80538 Munich, Germany

2. Department of Physics, Technische Universität München, James-Franck-Str. 1, 85748 Garching, Germany

3. Center for Advancing Electronics Dresden & Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01069 Dresden, Germany

4. Max Planck Institute of Microstructure Physics, Weinberg 2, 06120 Halle, Germany

Abstract

Regular and robust 2D conjugated organogold networks with anthra-tetrathiophene repeat units are synthesized by debrominative coupling on iodine-passivated Au(111). Dynamic error correction becomes feasibly through iodine-induced bond reversibility.

Funder

Deutsche Forschungsgemeinschaft

Bayerische Forschungsstiftung

Publisher

Royal Society of Chemistry (RSC)

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