The flexibility of long chain substituents influences spin-crossover in isomorphous lipid bilayer crystals

Author:

Galadzhun Iurii12345ORCID,Kulmaczewski Rafal12345,Shahid Namrah12345ORCID,Cespedes Oscar6275,Howard Mark J.12345,Halcrow Malcolm A.12345ORCID

Affiliation:

1. School of Chemistry

2. University of Leeds

3. Woodhouse Lane

4. Leeds

5. UK

6. School of Physics and Astronomy

7. Leeds LS2 9JT

Abstract

These two compounds are isomorphous but show different spin-state behaviour on cooling. This may be influenced by the packing of alkyl vs. alkynyl chains in the solid state.

Funder

Engineering and Physical Sciences Research Council

Diamond Light Source

University of Leeds

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference65 articles.

1. Spin Crossover in Transition Metal Compounds I−III: Topics in Current Chemistry , ed. P. Gütlich and H. A. Goodwin , Springer-Verlag , Berlin , 2004 , vol. 233–235

2. Spin-crossover materials – properties and applications , ed. M. A. Halcrow , John Wiley & Sons , Chichester, UK , 2013 , p. 568

3. Dynamic molecular crystals with switchable physical properties

4. Emerging trends in spin crossover (SCO) based functional materials and devices

5. Coupling Mechanical and Electrical Properties in Spin Crossover Polymer Composites

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