NHC ligand-powered palladium-catalyzed carbonylative C–S bond cleavage of vinyl sulfides: efficient access to tert-butyl arylacrylates
Author:
Affiliation:
1. Dalian National Laboratory for Clean Energy
2. Dalian Institute of Chemical Physics
3. Chinese Academy of Science
4. Dalian
5. China
6. Leibniz-Institut für Katalyse e.V. an der Universität Rostock
7. 18059 Rostock
8. Germany
Abstract
A palladium-catalyzed carbonylative C–S bond activation of divinyl sulfides to synthesize various tert-(E)-butyl arylacrylates under 1 bar of CO has been developed. A series of tert-(E)-butyl acrylates were obtained in moderate to good yields.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB02043E
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