Structural evolution induced preferential occupancy of designated cation sites by Eu2+ in M5(Si3O9)2 (M = Sr, Ba, Y, Mn) phosphors

Author:

Wei Yi.1234,Lin Chun Che56789,Quan Zewei1011124,Molokeev Maxim S.1314151617ORCID,Atuchin Victor V.1819202117,Chan Ting-Shan222324,Liang Yujun1234,Lin Jun252627284,Li Guogang1234

Affiliation:

1. Faculty of Materials Science and Chemistry

2. China University of Geosciences

3. Wuhan 430074

4. P. R. China

5. Condensed Matter and Interfaces

6. Debye Institute for Nanomaterials Science

7. Utrecht University

8. Princetonplein 5

9. 3584 CC Utrecht

10. Department of Chemistry

11. South University of Science and Technology of China

12. Shenzhen

13. Laboratory of Crystal Physics

14. Kirensky Institute of Physics

15. Siberian Branch of the Russian Academy of Sciences

16. Krasnoyarsk 660036

17. Russia

18. Laboratory of Optical Materials and Structures

19. Institute of Semiconductor Physics

20. SB RAS

21. Novosibirsk 630090

22. National Synchrotron Radiation Research Center

23. Hsinchu 300

24. Taiwan

25. State Key Laboratory of Rare Earth Resource Utilization

26. Changchun Institute of Applied Chemistry

27. Chinese Academy of Sciences

28. Changchun 130022

Abstract

A schematic presentation for the unexpected blue-shifted luminescence of Eu2+ in M5(Si3O9)2 (M = Sr, Ba, Y, Eu, Mn) based on the preferential occupancy at the designated cation sites.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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