Catalytic enantioselective synthesis of macrodiolides and their application in chiral recognition
Author:
Affiliation:
1. Key Laboratory of Green Chemistry & Technology
2. Ministry of Education
3. College of Chemistry
4. Sichuan University
5. Chengdu 610064
Abstract
An asymmetric tandem Friedel–Crafts alkylation/intermolecular macrolactonization of ortho-quinone methides with C3-substituted indoles was achieved by using a chiral N,N′-dioxide-scandium(iii) complex.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06162J
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