Reactivity of a half-lantern Pt2(ii,ii) complex with triphenylphosphine: selectivity in a protonation reaction-Reference-Cited by-同舟云学术

Reactivity of a half-lantern Pt2(ii,ii) complex with triphenylphosphine: selectivity in a protonation reaction

Published:2016 Issue:80 Volume:6 Page:76463-76472
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Niazi Maryam¹²³⁴,Shahsavari Hamid R.¹²³⁴^ORCID,Haghighi Mohsen Golbon¹⁵⁶⁴,Halvagar Mohammad Reza⁷⁸⁴,Hatami Samaneh¹²³⁴,Notash Behrouz¹⁵⁶⁴

Affiliation:

1. Department of Chemistry

2. Institute for Advanced Studies in Basic Sciences (IASBS)

3. Zanjan 45137-6731

4. Iran

5. Shahid Beheshti University

6. Tehran 19839-69411

7. Chemistry & Chemical Engineering Research Center of Iran

8. Tehran

Abstract

Reaction of PPh₃ with half-lantern complex [{Pt(ppy)(μ₂-Spy)}₂], 1, gave complex [Pt(ppy)(η¹-S-Spy)(PPh₃)], 2, as a result of platinum–nitrogen bonds dissociation. Complex 2 revealed anionic selectivity upon protonation reaction with acidic species.

Funder

Iran National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA15604E

Reference75 articles.

1. Half-Lantern Pt(II) and Pt(III) Complexes. New Cyclometalated Platinum Derivatives

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3. Redox-controlled Luminescence of a Cyclometalated Dinuclear Platinum Complex Bridged with Pyridine-2-thiolate Ions