Highly dispersed rhodium atoms supported on defect-rich Co(OH)2 for the chemoselective hydrogenation of nitroarenes

Author:

Fu Huan1,Zhang Huan1,Yang Guichun1,Liu Jun1,Xu Junyuan1,Wang Peihuan1,Zhao Ning2,Zhu Lihua13ORCID,Chen Bing Hui2

Affiliation:

1. College of Chemistry and Chemical Engineering, Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi, China

2. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

3. State Key Laboratory for Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Abstract

0.54% Rh/Co(OH)2 exhibited 100% selectivity for –NO2 hydrogenation at >96% conversion for nitroarene hydrogenation. Its excellent catalytic performance is due to the interfacial effect of Rh–Co(OH)2 and Rh in the form of single atoms and nanoclusters.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangxi Province

China Postdoctoral Science Foundation

Jiangxi University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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