Synthesis and reactivity of a PCcarbeneP cobalt(i) complex: the missing link in the cobalt PXP pincer series (X = B, C, N)-Reference-Cited by-同舟云学术

Synthesis and reactivity of a PCcarbeneP cobalt(i) complex: the missing link in the cobalt PXP pincer series (X = B, C, N)

Published:2018 Issue:43 Volume:9 Page:8234-8241
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sung Simon¹²³^ORCID,Wang Qingyang¹²³,Krämer Tobias¹⁴⁵^ORCID,Young Rowan D.¹²³^ORCID

Affiliation:

1. Department of Chemistry

2. National University of Singapore

3. Singapore 117543

4. Maynooth University

5. Ireland

Abstract

We report the first example of a cobalt PC_carbeneP pincer complex (1) featuring a central alkylidene carbon donor accessed through the dehydration of an alcoholic POP proligand.

Funder

National University of Singapore

Ministry of Education – Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02782J

Reference75 articles.

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2. Key factors in pincer ligand design

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4. Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation

5. Additive-Free Cobalt-Catalyzed Hydrogenation of Esters to Alcohols

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