Nanoceria-promoted low Pd–Ni catalyst for the synthesis of secondary amines from aliphatic alcohols and ammonia
Author:
Affiliation:
1. Eco-Efficient Products and Processes Laboratory (E2P2L)
2. UMI 3464 CNRS – Solvay
3. 201108 Shanghai
4. China
5. Solvay (China) Co., Ltd.
6. Solvay SpecialChem. SA
7. 75019 Paris
8. France
Abstract
Pd–Ni catalysts supported over nanoceria with very low Ni and Pd loading (<0.5 wt%) showed high activity and selectivity for the direct amination of 1-octanol with ammonia towards dioctylamine with 80% yield.
Funder
Agence Nationale de la Recherche
Science and Technology Commission of Shanghai Municipality
Shanghai Minhang Government
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CY/C8CY01670D
Reference54 articles.
1. H. A. Wittcoff , B. G.Reuben and J. S.Plotkin , Industrial Organic Chemicals , 2nd edn, Wiley , NY , 2004
2. S. A. Lawrence , Amines: Synthesis, Properties and Applications , Cambridge University Press , 2004
3. Catalytic Amination of Biomass-Based Alcohols
4. Methylamines synthesis: A review
5. Industrial processes for manufacturing amines
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