Facile and systematic access to the least-coordinating WCA [(RFO)3Al–F–Al(ORF)3]− and its more Lewis-basic brother [F–Al(ORF)3]− (RF = C(CF3)3)-Reference-Cited by-同舟云学术

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Facile and systematic access to the least-coordinating WCA [(RFO)3Al–F–Al(ORF)3]− and its more Lewis-basic brother [F–Al(ORF)3]− (RF = C(CF3)3)

Published:2018 Issue:35 Volume:9 Page:7058-7068
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Martens Arthur¹²³⁴⁵^ORCID,Weis Philippe¹²³⁴⁵^ORCID,Krummer Michael Christian¹²³⁴⁵,Kreuzer Marvin¹²³⁴⁵,Meierhöfer Andreas¹²³⁴⁵,Meier Stefan C.¹²³⁴⁵^ORCID,Bohnenberger Jan¹²³⁴⁵^ORCID,Scherer Harald¹²³⁴⁵,Riddlestone Ian¹²³⁴⁵^ORCID,Krossing Ingo¹²³⁴⁵^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie

2. Freiburger Materialforschungszentrum (FMF)

3. Universität Freiburg

4. 79104 Freiburg

5. Germany

Abstract

The least-coordinating anion [(R^FO)₃Al–F–Al(OR^F)₃]⁻ and its more Lewis-basic brother [F–Al(OR^F)₃]⁻ (R^F = C(CF₃)₃).

Funder

Albert-Ludwigs-Universität Freiburg

H2020 European Research Council

Deutsche Forschungsgemeinschaft

BASF Schweiz

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02591F

Reference54 articles.

1. Reactive p-block cations stabilized by weakly coordinating anions

2. Taming the Cationic Beast: Novel Developments in the Synthesis and Application of Weakly Coordinating Anions

3. A Systematic Investigation of Coinage Metal Carbonyl Complexes Stabilized by Fluorinated Alkoxy Aluminates

4. [Au(η 2 ‐C 2 H 4 ) 3 ] + [Al(OR F ) 4 ] – – a Stable Homoleptic (Ethene)gold Complex

5. Metastable Se6 as a ligand for Ag+: from isolated molecular to polymeric 1D and 2D structures

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