Nanocavity effects of various zeolite frameworks on n-pentane cracking to light olefins: combination studies of DFT calculations and experiments

Author:

Thivasasith Anawat12345,Maihom Thana67895ORCID,Pengpanich Sitthiphong10115,Wattanakit Chularat12345ORCID

Affiliation:

1. School of Energy Science and Engineering

2. Nanocatalysts and Nanomaterials for Sustainable Energy and Environment Research Network of NANOTEC

3. Vidyasirimedhi Institute of Science and Technology

4. Rayong 21210

5. Thailand

6. Department of Chemistry

7. Faculty of Liberal Arts and Science

8. Kasetsart University

9. Kamphaeng Saen Campus

10. PTT Global Chemical Public Company Limited (PTTGC)

11. Bangkok 10900

Abstract

Better control of light olefin product selectivity (ethylene and propylene) on various zeolite frameworks (H-FER, H-ZSM-5 and H-FAU) obtained from n-pentane catalytic cracking has attracted considerable attention from both scientific and petrochemical industrial viewpoints.

Funder

Vidyasirimedhi Institute of Science and Technology

Thailand Research Fund

Office of the Higher Education Commission

National Nanotechnology Center

Ministry of Science and Technology of Thailand

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference34 articles.

1. Catalytic cracking of hydrocarbons over modified ZSM-5 zeolites to produce light olefins: A review

2. C. Baerlocher , L. B.McCusker , D. H.Olson , C.Baerlocher , A. W.Burton , W. H.Baur , R. W.Broach , D. L.Dorset , R. X.Fischer , H.Gies , R. M.Kirchner , R. F.Lobo , L. B.McCusker , W. M.Meier , R. E.Morris , W. J.Mortier , M.O'Keeffe , D. H.Olson , M. M. J.Treacy , H.van Koningsveld and O.Terasaki , Atlas of Zeolite Framework Types , Elsevier Science B.V. , Amsterdam , 2007

3. Recent advances of pore system construction in zeolite-catalyzed chemical industry processes

4. NANOCAVITY EFFECTS ON N2O DECOMPOSITION ON DIFFERENT TYPES OF FE-ZEOLITES (Fe-FER, Fe-BEA, Fe-ZSM-5 AND Fe-FAU): A COMBINED THEORETICAL AND EXPERIMENTAL STUDY

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