Synthesis, structure, and reactions of a copper–sulfido cluster comprised of the parent Cu2S unit: {(NHC)Cu}2(μ-S)

Author:

Zhai Junjie1234,Filatov Alexander S.1234,Hillhouse Gregory L.1234,Hopkins Michael D.1234

Affiliation:

1. Department of Chemistry

2. The University of Chicago

3. Chicago

4. USA

Abstract

The first CuI2(μ-S) complex, {(IPr*)Cu}2(μ-S) (IPr* = 1,3-bis(2,6-(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene), has been synthesized, and its structure has been characterized crystallographically.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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