Cp2TiCl2-catalyzed hydrocarboxylation of alkynes with CO2: formation of α,β-unsaturated carboxylic acids-Reference-Cited by-同舟云学术

Cp2TiCl2-catalyzed hydrocarboxylation of alkynes with CO2: formation of α,β-unsaturated carboxylic acids

Published:2017 Issue:6 Volume:7 Page:3534-3539
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Shao Peng¹²³⁴⁵,Wang Sheng¹²³⁴⁵,Du Gaixia¹²³⁴⁵,Xi Chanjuan¹²³⁴⁵

Affiliation:

1. Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology

2. Ministry of Education

3. Department of Chemistry

4. Tsinghua University

5. Beijing 100084

Abstract

Cp₂TiCl₂-catalyzed hydrocarboxylation of alkynes with CO₂ (atmospheric pressure) has been reported. A range of alkynes were transformed to the corresponding α,β-unsaturated carboxylic acids in high yields with high regioselectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C6RA25003C

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