Fluorination-dependent molecular orbital occupancy in ring-shaped perfluorocarbons-Reference-Cited by-同舟云学术

Fluorination-dependent molecular orbital occupancy in ring-shaped perfluorocarbons

Published:2015 Issue:28 Volume:17 Page:18337-18343
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Brandenburg Tim¹²³⁴⁵,Petit Tristan¹²³⁴,Neubauer Antje¹²³⁴,Atak Kaan¹²³⁴⁵,Nagasaka Masanari⁶⁷⁸,Golnak Ronny¹²³⁴⁵,Kosugi Nobuhiro⁶⁷⁸,Aziz Emad F.¹²³⁴⁵

Affiliation:

1. Institute of Methods for Material Development

2. Helmholtz-Zentrum Berlin für Materialien und Energie

3. 12489 Berlin

4. Germany

5. Department of Physics

6. Institute for Molecular Science

7. Okazaki 444-8585

8. Japan

Abstract

Carbon K-edge absorption and emission spectra of liquid decalin are presented and compared to perfluorodecalin. A molecular orbital change from unoccupied to occupied orbitals induced through the fluorination process was observed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP01254F

Reference47 articles.

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4. Solubility of oxygen in liquid perfluorocarbons

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