Supramolecular organogel formation behaviors of beads-on-string shaped poly(azomethine)s dependent on POSS structures in the main chains
Author:
Affiliation:
1. Faculty of Molecular Chemistry and Engineering
2. Kyoto Institute of Technology
3. Kyoto 606-8585
4. Japan
5. Faculty of Material Science and Technology
6. Materials Innovation Lab
Abstract
Organogel formation was observed for isobutyl-substituted cage octasilsesquioxane (T8) in the main-chain type polyazomethines, while precipitates instead of gel formation were observed for phenyl-substituted double-decker-shaped silsesquioxanes (DDSQ)-poly(azomethine)s.
Funder
Ministry of Education, Culture, Sports, Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00346A
Reference37 articles.
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3. New Polymeric Materials Based on Element-Blocks
4. Advanced functional materials based on polyhedral oligomeric silsesquioxane (POSS)
5. Synthesis of single component element-block materials based on siloxane-based cage frameworks
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1. Phenyl-Substituted Cage Silsesquioxane-Based Star-Shaped Giant Molecular Clusters: Synthesis, Properties, and Surface Segregation Behavior;Langmuir;2024-05-17
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3. Well‐defined difunctional POSS macromers and related organic–inorganic polymers: Precision synthesis, structure and properties;Journal of Polymer Science;2023-11-10
4. Tripod-shaped POSS compounds as single-component silsesquioxane hybrids;Polymer Journal;2023-09-27
5. Synthesis of Low-Dielectric Polyureas by Incorporating Phenyl-Substituted Cage Silsesquioxanes in the Main Chain;ACS Applied Polymer Materials;2023-07-03
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