Role(s) of TMA in polymerization
Author:
Affiliation:
1. Dipartimento di Scienze Chimiche
2. Università di Napoli Federico II
3. 80126 Napoli
4. Italy
5. Department of Chemistry
6. University of Manitoba
7. Winnipeg
8. Canada
Abstract
A new TMA-metallocene binding mode is presented and its role in entropy compensation in insertion chemistry discussed.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04895H
Reference76 articles.
1. Group 4 metallocene polymerisation catalysts: quantification of ring substituent steric effects
2. Effect of the Nature of Metallocene Complexes of Group IV Metals on Their Performance in Catalytic Ethylene and Propylene Polymerization
3. Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts
4. The Chemistry of Catalyst Activation: The Case of Group 4 Polymerization Catalysts
5. Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships
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