An investigation of steric influence on the reactivity of Fe<sup>V</sup>(O)(OH) tautomers in stereospecific C

An investigation of steric influence on the reactivity of Fe^V(O)(OH) tautomers in stereospecific C–H hydroxylation

Published:2023 Issue:12 Volume:52 Page:3596-3609
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mitra Mainak¹²^ORCID,Brinkmeier Alexander¹,Li Yong¹,Borrell Margarida³^ORCID,Call Arnau³^ORCID,Lloret Fillol Julio⁴^ORCID,Richmond Michael G.⁵^ORCID,Costas Miquel³^ORCID,Nordlander Ebbe¹^ORCID

Affiliation:

1. Chemical Physics, Department of Chemistry, Lund University, Box 124, SE-221 00, Lund, Sweden

2. Department of Chemistry, Burdwan Raj College, Aftab Avenue, W.B. 713104, India

3. QBIS-CAT, Department of Chemistry and Institut de Quimica Computacional i Catàlisi, University of Girona, Campus Montilivi, E-17071 Girona, Spain

4. Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Avinguda Paisos Catalans 16, 43007, Tarragona, Spain

5. Department of Chemistry, University of North Texas, Denton, Texas 76203, USA

Abstract

The steric properties of the tetradentate ligand influences the reactivities of the Fe(v)O units in a number of tautomeric Fe(v)(O)(OH) complexes.

Funder

European Commission

China Scholarship Council

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT00725H

Reference52 articles.

1. 3d Transition Metals for C–H Activation

2. Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

3. Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

4. Biologically inspired oxidation catalysis

5. Rieske non-heme iron-dependent oxygenases catalyse diverse reactions in natural product biosynthesis