Cleavage of cluster iron–sulfide bonds in cyclophane-coordinated FenSm complexes-Reference-Cited by-同舟云学术

Cleavage of cluster iron–sulfide bonds in cyclophane-coordinated FenSm complexes

Published:2021 Issue:3 Volume:50 Page:816-821
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Buratto William R.¹²³⁴⁵,Ferreira Ricardo B.¹²³⁴⁵^ORCID,Catalano Vincent J.¹⁶⁷⁵,García-Serres Ricardo⁸⁹¹⁰¹¹¹²^ORCID,Murray Leslie J.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Center for Catalysis

3. University of Florida

4. Gainesville

5. USA

6. University of Nevada

7. Reno

8. LCBM/PMB and CEA

9. iRTSV/CBM/PMB and CNRS

10. Université Grenoble Alpes

11. UMR 5249

12. LCBM/PMB

Abstract

Reaction of the tri- or di(μ-sulfido)triiron(iii) complexes, Fe₃S₃L^Et/Me (1) or Fe₂S₂HL^Et/Me (5), with Fe₃Br₃L^Et/Me (2) results in electron and ligand redistribution to yield the mixed-ligand complexes, including Fe₃Br₂SL^Et/Me (3) and Fe₂Br₂SHL^Et/Me (4).

Funder

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03805A

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