Towards the upgrading of fermentation broths to advanced biofuels: a water tolerant catalyst for the conversion of ethanol to isobutanol

Author:

Pellow Katy J.1234ORCID,Wingad Richard L.1234ORCID,Wass Duncan F.1234ORCID

Affiliation:

1. School of Chemistry

2. University of Bristol

3. Bristol

4. UK

Abstract

The conversion of methanol/ethanol mixtures to isobutanol with the pre-catalyst trans-[RuCl2(dppm)2] (1) is tolerant to the addition of water to the system, achieving an isobutanol yield of 36% at 78% selectivity with water concentrations typical of that of a crude fermentation broth.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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