Ligand stabilization of manganocene dianions – in defiance of the 18-electron rule-Reference-Cited by-同舟云学术

Ligand stabilization of manganocene dianions – in defiance of the 18-electron rule

Published:2019 Issue:44 Volume:21 Page:24300-24307
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Yadav Monalisa¹²³⁴,Fang Hong⁵⁶⁷⁸^ORCID,Giri Santanab⁹¹⁰⁴^ORCID,Jena Puru⁵⁶⁷⁸^ORCID

Affiliation:

1. IISER Kolkata

2. Haringhata Farm

3. Nadia

4. India

5. Physics Department

6. Virginia Commonwealth University

7. Richmond

8. USA

9. School of Applied Sciences and Humanities, Haldia institute of Technology

10. Haldia

Abstract

Di-anions of manganocene derivatives complexes, in spite of being a 19-electron system, are found to be more stable than their mono-anions. This defiance of the 18-electron rule is linked to the geometrical distortion of the di-anion, akin to the Jahn-Teller-like mechanism.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP02331C

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